I feel generous today, so here you go:
There are 3 types of scrolls: Scroll of Purification, Scroll of Deception, Scroll of Illusion.
Purification clears a transmog from an item, returning it to the original model. It is only needed for returning an item to it's original model. If you find a cooler option for your item, you can just apply a new mog on it and it will be overwritten.
Deception can be used on uncommon to epic quality items (so greens, blues, purples) to get their essence, which you apply on a 2nd item to look like the 1st. (You use it to make Shadowmourne look like something else).
Illusion is the same as deceotion, but it is used to capture legendary appearances so you can apply them on something else (You make other things look like Shadowmourne).
All 3 scrolls have a random chance to drop upon killing any WotLK raid boss, and upon winning a BG. Chances are obviously much less for Scrolls of Illusion than for others. No exact drop rate was or will be published. You do not loot those scrolls, they will simply appear in your bags if you're lucky enough. If bags are full you well get them in the mailbox. The scrolls are soulbound, and they drop for everyone, doesn't matter if you disable the transmog feature or not.
Now as far as mogging rules go, it's divided into 2 categories:
No matter the item type, you cannot mog your gear to grey items. You can mog heirlooms but they are reverted to their original form when sent through mail.
Weapons:
You can only mog weapon types that belong in the same group as follows {2h Axes, 2h Swords, 2h Maces}, {Staves, Polearms}, {1h Axes, 1h Swords, 1h Maces} {Bows, Crossbows}, {Daggers} {Fist weapons}*
1h and offhand weapons work with each other assuming of course they are in the same weapon category.
Armor:
All of the following rules apply:
1. Plate to plate, cloth to cloth and so on.
2. Class specific gear only works on the respective class (You cannot mog warlock sets on a mage, even though it's all cloth gear)
3. You must meet the prerequisites of equipping the item beforehand. If for example you have a pair of Engineering goggles of the same item type as your headpiece, you need to have the minimum Engineering skill to equip said goggles before being able to use a scroll on them. Rule 2 is part of this, you can't equip sets from other classes, therefore you cannot mog them.
* I am not 100% sure Daggers and Fist don't work with one another, someone please correct me if I am wrong
Sorry for the long post, I'll skip the potato.
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