Buying plans for Adamantite Items for Blacksmithing.

Hi, I'm currently leveling my blacksmithing in Frostmourne and I've reached skill level 335 where everything trained from the trainer is yellow or green. I know that I should be able to buy the following plan/recipe:
https://www.wowhead.com/item=23594/p...acers#comments
and two more from a vendor in Shadowmoon Valley:
https://www.wowhead.com/npc=19342/krek-cragcrush

But he does not sell them. I think they are limited quantity but do you know if I can actually buy them from him or what the respawn rate is?